{"id":305758,"date":"2024-10-19T20:56:03","date_gmt":"2024-10-19T20:56:03","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bs-iso-150332018\/"},"modified":"2024-10-25T18:30:56","modified_gmt":"2024-10-25T18:30:56","slug":"bs-iso-150332018","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bs-iso-150332018\/","title":{"rendered":"BS ISO 15033:2018"},"content":{"rendered":"
This document describes a high-performance liquid chromatography (HPLC) method for determining the concentrations of cyclic oligomers of caprolactam, from 0,01 % by mass upwards, and linear oligomers of caprolactam, from 5 mg\/kg upwards, both up to and including the hexamer of caprolactam (n<\/i> = 6), in samples of polyamide 6, caprolactam and mixtures of rearrangement products in water.<\/p>\n
A second, significantly faster, HPLC method is included for determination of caprolactam and its cyclic dimer, based on the same principle and using the same equipment as the first method.<\/p>\n
PDF Pages<\/th>\n | PDF Title<\/th>\n<\/tr>\n | ||||||
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2<\/td>\n | National foreword <\/td>\n<\/tr>\n | ||||||
6<\/td>\n | Foreword <\/td>\n<\/tr>\n | ||||||
7<\/td>\n | Introduction <\/td>\n<\/tr>\n | ||||||
9<\/td>\n | 1 Scope 2 Normative references 3 Terms and definitions 4 Principle 5 Reagents <\/td>\n<\/tr>\n | ||||||
11<\/td>\n | 6 Apparatus <\/td>\n<\/tr>\n | ||||||
12<\/td>\n | 7 Test sample 8 Procedure 8.1 Calibration 8.1.1 Method A <\/td>\n<\/tr>\n | ||||||
13<\/td>\n | 8.1.2 Method B 8.2 Determination 8.2.1 Method A <\/td>\n<\/tr>\n | ||||||
15<\/td>\n | 8.2.2 Method B 9 Calculations 9.1 Calculation of calibration factors 9.1.1 Calibration factors for cyclic oligomers <\/td>\n<\/tr>\n | ||||||
16<\/td>\n | 9.1.2 Calibration factors for linear oligomers 9.2 Test sample 9.2.1 Calculation of cyclic oligomer concentrations <\/td>\n<\/tr>\n | ||||||
17<\/td>\n | 9.2.2 Calculation of linear oligomer concentrations 10 Precision <\/td>\n<\/tr>\n | ||||||
18<\/td>\n | 11 Test report <\/td>\n<\/tr>\n | ||||||
19<\/td>\n | Annex A (normative) HPLC parameters and injector programme \u2014 Using eluent A <\/td>\n<\/tr>\n | ||||||
20<\/td>\n | Annex B (normative) HPLC parameters and injector programme \u2014 Using eluent B <\/td>\n<\/tr>\n | ||||||
21<\/td>\n | Annex C (informative) Schematic diagram of HPLC apparatus <\/td>\n<\/tr>\n | ||||||
22<\/td>\n | Bibliography <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":" Plastics. Determination of caprolactam and its cyclic and linear oligomers by HPLC<\/b><\/p>\n |