{"id":305764,"date":"2024-10-19T20:56:05","date_gmt":"2024-10-19T20:56:05","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bs-iso-214002018\/"},"modified":"2024-10-25T18:30:55","modified_gmt":"2024-10-25T18:30:55","slug":"bs-iso-214002018","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bs-iso-214002018\/","title":{"rendered":"BS ISO 21400:2018"},"content":{"rendered":"
This document specifies procedures for the laboratory determination of the total elemental sulfur and the sulfate half-ester content of cellulose nanocrystals (CNCs) by inductively coupled plasma-optical emission spectroscopy and conductometric titration, respectively, including sample preparation, measurement methods and data analysis.<\/p>\n
This document is applicable to the characterization of CNCs:<\/p>\n
with all monovalent counterions (particularly hydronium and sodium cations);<\/p>\n<\/li>\n
which are either in the never-dried state in aqueous suspension, or have been redispersed from a dried form; and<\/p>\n<\/li>\n
which have been extracted from any naturally occurring cellulose source using a range of sulfuric acid hydrolysis conditions, or have been sulfated post-hydrolysis using sulfuric acid.<\/p>\n<\/li>\n<\/ol>\n
PDF Pages<\/th>\n | PDF Title<\/th>\n<\/tr>\n | ||||||
---|---|---|---|---|---|---|---|
2<\/td>\n | National foreword <\/td>\n<\/tr>\n | ||||||
6<\/td>\n | Foreword <\/td>\n<\/tr>\n | ||||||
7<\/td>\n | Introduction <\/td>\n<\/tr>\n | ||||||
9<\/td>\n | 1 Scope 2 Normative references 3 Terms and definitions <\/td>\n<\/tr>\n | ||||||
11<\/td>\n | 4 Symbols and abbreviated terms <\/td>\n<\/tr>\n | ||||||
12<\/td>\n | 5 Total elemental sulfur content \u2014 ICP-OES method 5.1 Principle <\/td>\n<\/tr>\n | ||||||
13<\/td>\n | 5.2 Reagents and apparatus <\/td>\n<\/tr>\n | ||||||
14<\/td>\n | 5.3 Sample purification by dialysis <\/td>\n<\/tr>\n | ||||||
16<\/td>\n | 5.4 Microwave-assisted sample digestion and sample preparation <\/td>\n<\/tr>\n | ||||||
18<\/td>\n | 5.5 Preparation of calibration solutions and blanks <\/td>\n<\/tr>\n | ||||||
19<\/td>\n | 5.6 Analysis of standards and samples by ICP-OES <\/td>\n<\/tr>\n | ||||||
20<\/td>\n | 5.7 Calculation of dry CNC total elemental sulfur content and CNC surface charge <\/td>\n<\/tr>\n | ||||||
21<\/td>\n | 5.8 Test report 6 Sulfate half-ester content \u2014 Conductometric titration method 6.1 Principle 6.2 Reagents and apparatus <\/td>\n<\/tr>\n | ||||||
23<\/td>\n | 6.3 Sample purification by dialysis <\/td>\n<\/tr>\n | ||||||
24<\/td>\n | 6.4 Sample protonation by ion exchange <\/td>\n<\/tr>\n | ||||||
25<\/td>\n | 6.5 Sample analysis by conductometric titration <\/td>\n<\/tr>\n | ||||||
26<\/td>\n | 6.6 Calculation of dry CNC sulfate half-ester content and CNC surface charge <\/td>\n<\/tr>\n | ||||||
28<\/td>\n | 6.7 Test report <\/td>\n<\/tr>\n | ||||||
29<\/td>\n | Annex A (normative) Sample digestion by wet ashing <\/td>\n<\/tr>\n | ||||||
31<\/td>\n | Annex B (normative) Sample protonation by batch treatment with ion exchange resin <\/td>\n<\/tr>\n | ||||||
32<\/td>\n | Annex C (informative) Precision <\/td>\n<\/tr>\n | ||||||
34<\/td>\n | Bibliography <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":" Pulp. Determination of cellulose nanocrystal sulfur and sulfate half-ester content<\/b><\/p>\n |