{"id":445942,"date":"2024-10-20T08:44:18","date_gmt":"2024-10-20T08:44:18","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bs-en-178132023\/"},"modified":"2024-10-26T16:16:40","modified_gmt":"2024-10-26T16:16:40","slug":"bs-en-178132023","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bs-en-178132023\/","title":{"rendered":"BS EN 17813:2023"},"content":{"rendered":"

This document specifies an empirical method for the simultaneous direct determination of the fluorine, chlorine, bromine, and sulfur content in environmental solid matrices by oxidative pyrohydrolytic combustion at (1 050 \u00b1 50) \u00b0C, followed by ion chromatography. The method is applicable for the determination of concentrations \u2265 10 mg\/kg of each element based on dry matter. The upper limit and exact concentration range covered depends on the blank levels of the instrumentation and the capacity of the chromatographic separation column used for determination. NOTE 1 Simultaneous determination of iodine content is possible but currently not validated. NOTE 2 Other detection methods can be applied if validated.<\/p>\n

PDF Catalog<\/h4>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
PDF Pages<\/th>\nPDF Title<\/th>\n<\/tr>\n
2<\/td>\nundefined <\/td>\n<\/tr>\n
6<\/td>\n1 Scope
2 Normative references
3 Terms and definitions
4 Principle <\/td>\n<\/tr>\n
7<\/td>\n5 Interferences
5.1 Interferences during combustion
5.2 Interferences during absorption
5.3 Interferences during ion chromatography
6 Reagents and gases
6.1 General
6.2 Reagents for ion chromatography
6.2.1 Eluents <\/td>\n<\/tr>\n
8<\/td>\n6.2.2 Water, with a resistivity of \u2265 18 M\u03a9 cm (25 \u00b0C)
6.2.3 Sodium carbonate (anhydrous), Na2CO3
6.2.3.1 Sodium carbonate concentrate, c(Na2CO3) = 0,09 mol\/l
6.2.3.2 Sodium carbonate eluent, c(Na2CO3) = 0,009 mol\/l
6.2.4 Bromide, chloride, fluoride, and sulfate stock solutions, c = 1 000 mg\/l of each anion
6.2.5 Bromide, chloride, fluoride, and sulfate standard solutions
6.2.5.1 General
6.2.5.2 Example of a bromide, chloride, fluoride, and sulfate mixed standard solution, c = 100 mg\/l of each anion <\/td>\n<\/tr>\n
9<\/td>\n6.2.5.3 Example of bromide, chloride, fluoride, and sulfate mixed calibration solutions
6.3 Reagents and gases for combustion
6.3.1 Inert gas, for example argon, \u2265 99,9 % (v\/v) purity
6.3.2 Oxygen, \u2265 99,9 % (v\/v) purity
6.4 Control standard
6.4.1 General
6.4.2 4-Bromobenzoic acid, C7H5BrO2, \u2265 99 % (m\/m) purity, CAS no. 586-76-5
6.4.3 4-Chlorobenzoic acid, C7H5ClO2, \u2265 99 % (m\/m) purity, CAS no. 74-11-3
6.4.4 Dibenzothiophene, C12H8S, \u2265 99 % (m\/m) purity, CAS no. 132-65-0
6.4.5 4-Fluorobenzoic acid, C7H5FO2, \u2265 99 % (m\/m) purity, CAS no. 456-22-4
6.4.6 Xylene, C8H10, analytical grade, CAS no. 1330-20-7
6.4.7 Example of a bromine, chlorine, fluorine, and sulfur control standard solution, c = 1 000 mg\/l of each element
6.4.8 Example of a bromine, chlorine, fluorine, and sulfur control standard solution, c = 10 mg\/l and 100 mg\/l of each element <\/td>\n<\/tr>\n
10<\/td>\n6.5 Reagents for absorption
6.5.1 General
6.5.2 Hydrogen peroxide solution, H2O2, approx. 30 % (m\/m), electronic grade
6.5.2.1 Absorption solution containing hydrogen peroxide, c(H2O2) \u2248 330 mg\/l
6.5.3 Sodium methane sulfonate, CH3SO3Na
6.5.3.1 Sodium methane sulfonate solution, c(CH3SO3Na) = 500 mg\/l
6.5.3.2 Absorption solution containing sodium methane sulfonate, c(CH3SO3Na) = 1 mg\/l
7 Apparatus
7.1 Combustion apparatus
7.1.1 Combustion furnace <\/td>\n<\/tr>\n
11<\/td>\n7.1.2 Combustion vessel
7.1.3 Absorption vessel
7.2 Ion chromatography (IC) system
7.2.1 General <\/td>\n<\/tr>\n
12<\/td>\n7.2.2 Eluent storage container
7.2.3 High pressure pump
7.2.4 Sample injection system
7.2.5 Guard column
7.2.6 Separation column
7.2.7 Conductivity detector and suppressor device
7.2.8 Data handling unit
7.2.9 Quality of the separation system <\/td>\n<\/tr>\n
13<\/td>\n8 Sampling and sample preparation
9 Procedure
9.1 Combustion
9.1.1 General <\/td>\n<\/tr>\n
14<\/td>\n9.1.2 Blank determination
9.2 Absorption
9.3 Ion chromatography
9.3.1 General
9.3.2 Calibration <\/td>\n<\/tr>\n
15<\/td>\n9.3.3 Measurement
9.4 Initial and daily checks
9.4.1 Initial laboratory capability check
9.4.2 Daily check <\/td>\n<\/tr>\n
16<\/td>\n10 Calculation
11 Expression of result
12 Test report <\/td>\n<\/tr>\n
17<\/td>\nAnnex A (informative)Performance characteristics <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":"

Environmental solid matrices. Determination of halogens and sulfur by oxidative pyrohydrolytic combustion followed by ion chromatography<\/b><\/p>\n\n\n\n\n
Published By<\/td>\nPublication Date<\/td>\nNumber of Pages<\/td>\n<\/tr>\n
BSI<\/b><\/a><\/td>\n2023<\/td>\n24<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"featured_media":445952,"template":"","meta":{"rank_math_lock_modified_date":false,"ep_exclude_from_search":false},"product_cat":[1000,2641],"product_tag":[],"class_list":{"0":"post-445942","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-71-040-40","7":"product_cat-bsi","9":"first","10":"instock","11":"sold-individually","12":"shipping-taxable","13":"purchasable","14":"product-type-simple"},"_links":{"self":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product\/445942","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/types\/product"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/media\/445952"}],"wp:attachment":[{"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/media?parent=445942"}],"wp:term":[{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product_cat?post=445942"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/pdfstandards.shop\/wp-json\/wp\/v2\/product_tag?post=445942"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}