{"id":341812,"date":"2024-10-19T23:58:23","date_gmt":"2024-10-19T23:58:23","guid":{"rendered":"https:\/\/pdfstandards.shop\/product\/uncategorized\/bs-en-71-52015-tc\/"},"modified":"2024-10-25T23:11:47","modified_gmt":"2024-10-25T23:11:47","slug":"bs-en-71-52015-tc","status":"publish","type":"product","link":"https:\/\/pdfstandards.shop\/product\/publishers\/bsi\/bs-en-71-52015-tc\/","title":{"rendered":"BS EN 71-5:2015 – TC"},"content":{"rendered":"
This European Standard specifies requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are: ? those classified as dangerous by the EC-legislation applying to dangerous substances and dangerous mixtures [5]; ? substances and mixtures which in excessive amounts could harm the health of the children using them and which are not classified as dangerous by the above mentioned legislation; and ? any other chemical substance(s) and mixture(s) delivered with the chemical toy. NOTE The terms \u201csubstance\u201d and \u201c mixture\u201d are defined in the REACH regulation No. (EC)1907\/2006 and in the CLP regulation (EC) No. 1272\/2008. Additionally, requirements are specified for markings, warnings, safety rules, contents list, instructions for use and first aid information. This Part of EN 71 applies to: ? plaster of Paris (gypsum) moulding sets; ? ceramic and vitreous enamelling materials supplied in miniature workshop sets; ? oven-hardening plasticised PVC modelling clay sets; ? plastic moulding sets; ? embedding sets; ? adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents), supplied or recommended in model sets.<\/p>\n
PDF Pages<\/th>\n | PDF Title<\/th>\n<\/tr>\n | ||||||
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126<\/td>\n | 1 Scope 2 Normative references <\/td>\n<\/tr>\n | ||||||
127<\/td>\n | 3 Terms and definitions <\/td>\n<\/tr>\n | ||||||
128<\/td>\n | 4 Plaster of Paris (gypsum) moulding sets 4.1 Marking 4.2 First aid information 4.3 Safety rules <\/td>\n<\/tr>\n | ||||||
129<\/td>\n | 5 Oven-hardening plasticised PVC modelling clay sets 5.1 Chemical substances 5.2 Marking 5.3 First aid information <\/td>\n<\/tr>\n | ||||||
130<\/td>\n | 5.4 Safety rules 6 Moulding sets 6.1 Polystyrene granules sets 6.1.1 Chemical substances 6.1.2 Marking 6.1.3 First aid information <\/td>\n<\/tr>\n | ||||||
131<\/td>\n | 6.1.4 Safety rules 6.2 Embedding sets 6.2.1 General 6.2.2 Packaging 6.2.3 Marking 6.2.4 First aid information 6.2.5 Safety rules <\/td>\n<\/tr>\n | ||||||
132<\/td>\n | 7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets 7.1 General 7.2 Adhesives 7.2.1 Water-based adhesives 7.2.1.1 General 7.2.1.2 Liquid adhesives for paper and wood <\/td>\n<\/tr>\n | ||||||
134<\/td>\n | 7.2.1.3 Adhesive sticks and pastes for paper <\/td>\n<\/tr>\n | ||||||
135<\/td>\n | 7.2.2 Solvent-based adhesives 7.2.2.1 General 7.2.2.2 Multi-purpose adhesives 7.2.2.3 Contact adhesives <\/td>\n<\/tr>\n | ||||||
136<\/td>\n | 7.2.2.4 Special adhesives <\/td>\n<\/tr>\n | ||||||
137<\/td>\n | 7.2.2.5 Packaging 7.2.2.6 Marking 7.2.2.7 First aid information <\/td>\n<\/tr>\n | ||||||
138<\/td>\n | 7.2.2.8 Safety rules 7.3 Water-based paints or lacquers 7.3.1 General 7.3.2 Packaging 7.3.3 Marking <\/td>\n<\/tr>\n | ||||||
139<\/td>\n | 7.3.4 First aid information 7.3.5 Safety rules 7.4 Solvent-based paints, lacquers, thinners and cleaning solvents 7.4.1 General <\/td>\n<\/tr>\n | ||||||
140<\/td>\n | 7.4.2 Packaging 7.4.3 Marking 7.4.4 First aid information <\/td>\n<\/tr>\n | ||||||
141<\/td>\n | 7.4.5 Safety rules 8 Marking 8.1 General 8.2 Marking of the primary packaging 8.2.1 General 8.2.2 Manufacturer\u2019s identification 8.2.3 Warning phrases <\/td>\n<\/tr>\n | ||||||
142<\/td>\n | 8.3 Marking of individual containers and any packagings 9 Instructions for use 9.1 General 9.2 Contents list 9.3 Advice for adult supervision <\/td>\n<\/tr>\n | ||||||
143<\/td>\n | 9.4 Safety rules 9.5 Instructions for carrying out the activities 9.6 Spills and disposal of chemicals <\/td>\n<\/tr>\n | ||||||
144<\/td>\n | 10 Test methods 10.1 General 10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets 10.2.1 Principle 10.2.2 Standards and reagents 10.2.2.1 Standards <\/td>\n<\/tr>\n | ||||||
145<\/td>\n | 10.2.2.2 Reagents 10.2.3 Apparatus <\/td>\n<\/tr>\n | ||||||
146<\/td>\n | 10.2.4 Preparation of standard solutions 10.2.4.1 Stock solutions <\/td>\n<\/tr>\n | ||||||
147<\/td>\n | 10.2.4.2 Calibration solutions 10.2.4.3 Stability of standard solutions 10.2.5 Sampling <\/td>\n<\/tr>\n | ||||||
148<\/td>\n | 10.2.6 Sample preparation 10.2.7 Procedure 10.2.7.1 General 10.2.7.2 Extraction of citric acid esters and alkylsulfonic acid esters 10.2.7.3 Extraction of adipic acid polyesters 10.2.7.4 Evaporation of the solvent and weighing <\/td>\n<\/tr>\n | ||||||
149<\/td>\n | 10.2.7.5 Blank determination 10.2.7.6 GC-MSD determination of citric acid esters and alkylsulfonic acid esters 10.2.7.7 ATR-FT-IR identification of adipic acid polyesters 10.2.8 Evaluation of results 10.2.8.1 Calculation of solvent-extractable content containing plasticisers <\/td>\n<\/tr>\n | ||||||
150<\/td>\n | 10.2.8.2 Calculation and identification of plasticiser content by GC-MS analysis <\/td>\n<\/tr>\n | ||||||
151<\/td>\n | 10.2.9 Test report 10.3 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and polystyrene granules sets 10.3.1 Principle <\/td>\n<\/tr>\n | ||||||
152<\/td>\n | 10.3.2 Standards and reagents 10.3.3 Apparatus 10.3.3.1 Gas chromatograph with mass spectrometer detector (GC-MS) <\/td>\n<\/tr>\n | ||||||
153<\/td>\n | 10.3.3.2 Headspace analysis conditions 10.3.3.3 Other laboratory equipment <\/td>\n<\/tr>\n | ||||||
154<\/td>\n | 10.3.4 Preparation of standard solutions 10.3.5 Sampling 10.3.6 Sample preparation 10.3.7 Procedure 10.3.8 Evaluation of results <\/td>\n<\/tr>\n | ||||||
155<\/td>\n | 10.3.9 Test report 10.3.10 Critical control points 10.4 Determination of styrene content in polystyrene granules 10.4.1 Principle 10.4.2 Standards and reagents 10.4.2.1 Standards <\/td>\n<\/tr>\n | ||||||
156<\/td>\n | 10.4.2.2 Reagents 10.4.3 Apparatus <\/td>\n<\/tr>\n | ||||||
157<\/td>\n | 10.4.4 Preparation of the standard solutions 10.4.5 Sampling 10.4.6 Sample preparation 10.4.7 Procedure 10.4.8 Evaluation of results 10.4.9 Test report <\/td>\n<\/tr>\n | ||||||
158<\/td>\n | 10.5 Determination of organic solvents 10.5.1 General <\/td>\n<\/tr>\n | ||||||
160<\/td>\n | 10.5.2 Principle <\/td>\n<\/tr>\n | ||||||
161<\/td>\n | 10.5.3 Standards and reagents 10.5.3.1 Standards <\/td>\n<\/tr>\n | ||||||
162<\/td>\n | 10.5.3.2 Reagents 10.5.4 Apparatus <\/td>\n<\/tr>\n | ||||||
164<\/td>\n | 10.5.5 Preparation of the standard solutions 10.5.5.1 Stock solutions for the identification and determination of solvents using HS-GC-FID <\/td>\n<\/tr>\n | ||||||
165<\/td>\n | 10.5.5.2 Stock solutions for the identification and determination of solvents using GC-MS <\/td>\n<\/tr>\n | ||||||
166<\/td>\n | 10.5.5.3 Stock solution for the identification and determination of propane-1,2-diol 10.5.5.4 Calibration solutions <\/td>\n<\/tr>\n | ||||||
171<\/td>\n | 10.5.6 Sampling 10.5.7 Sample preparation 10.5.7.1 General <\/td>\n<\/tr>\n | ||||||
172<\/td>\n | 10.5.7.2 Sample preparation for identification and determination of solvents by HS-GC-FID 10.5.7.3 Sample preparation for identification of solvents by GC-MS 10.5.7.4 Sample preparation for determination of certain solvents by GC-MS <\/td>\n<\/tr>\n | ||||||
173<\/td>\n | 10.5.7.5 Sample preparation for determination of propane-1,2-diol using GC-FID 10.5.8 Procedure 10.5.8.1 Identification of solvents using HS-GC-FID <\/td>\n<\/tr>\n | ||||||
176<\/td>\n | 10.5.8.2 Identification of solvents using GC-MS <\/td>\n<\/tr>\n | ||||||
177<\/td>\n | 10.5.8.3 Determination of solvent content by HS-GC-FID <\/td>\n<\/tr>\n | ||||||
178<\/td>\n | 10.5.8.4 Determination of solvent content using GC-MS 10.5.8.5 Determination of propane-1,2-diol by GC-FID 10.5.8.6 Blank determination 10.5.9 Evaluation of results 10.5.9.1 Calculation of solvent content by HS-GC-FID <\/td>\n<\/tr>\n | ||||||
179<\/td>\n | 10.5.9.2 Calculation of solvent content by GC-MS or GC-FID 10.5.10 Test report 10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints or lacquers 10.6.1 Principle <\/td>\n<\/tr>\n | ||||||
180<\/td>\n | 10.6.2 Determination of total extract 10.6.2.1 Standards and reagents 10.6.2.2 Apparatus 10.6.2.3 Sampling 10.6.2.4 Sample preparation <\/td>\n<\/tr>\n | ||||||
181<\/td>\n | 10.6.2.5 Procedure 10.6.2.6 Evaluation of results 10.6.3 Identification of nitrocellulose 10.6.3.1 Principle 10.6.3.2 Reagents 10.6.3.3 Apparatus <\/td>\n<\/tr>\n | ||||||
182<\/td>\n | 10.6.3.4 Sampling 10.6.3.5 Sample preparation 10.6.3.6 Procedure 10.6.3.7 Evaluation of results <\/td>\n<\/tr>\n | ||||||
183<\/td>\n | 10.6.4 Determination of plasticisers 10.6.4.1 Principle 10.6.4.2 Standards and reagents 10.6.4.3 Apparatus 10.6.4.4 Preparation of the standard solution 10.6.4.5 Procedure 10.6.4.6 Evaluation of results 10.6.5 Determination of film-forming agents 10.6.5.1 Principle <\/td>\n<\/tr>\n | ||||||
184<\/td>\n | 10.6.5.2 Standards and reagents 10.6.5.3 Apparatus <\/td>\n<\/tr>\n | ||||||
187<\/td>\n | 10.6.5.4 Preparation of standard solutions <\/td>\n<\/tr>\n | ||||||
188<\/td>\n | 10.6.5.5 Sampling 10.6.5.6 Procedure 10.6.5.7 Evaluation of results <\/td>\n<\/tr>\n | ||||||
189<\/td>\n | 10.6.6 Determination of the modifiers 10.6.7 Test report <\/td>\n<\/tr>\n<\/table>\n","protected":false},"excerpt":{"rendered":" Tracked Changes. Safety of toys – Chemical toys (sets) other than experimental sets<\/b><\/p>\n |